Industry Trends, Technical Parameters, Applications, and Custom Solutions
Potassium Ethylxanthate (KEX; CAS No. 140-89-6) has become a cornerstone reagent in the global mining and metallurgical sector, offering unmatched efficacy in the separation of valuable metal ores via flotation technology. With the rapid advancement of extractive metallurgy, the technological evolution of reagents like potassium ethylxanthate has enabled industries to achieve higher yields, cost-efficiency, and compliance with increasingly stringent environmental standards.
Overview of Potassium Ethylxanthate and Industry Trends
Potassium Ethylxanthate is a potent chemical collector used in the flotation of sulfide ores, notably copper, zinc, and lead. Its formula is C2H5OCSSK (Potassium Ethyl Xanthate Formula), and it is distinguished by its rapid collecting power and selectivity in complex mineral processing circuits. According to ResearchAndMarkets, the global xanthates market, spearheaded by potassium ethyl xanthate, is projected to show a CAGR of 6.5% between 2023 and 2030 with escalating demand from Asia-Pacific's mining industry.
Potassium Ethylxanthate Specifications & Technical Parameters
Property |
Parameter |
Industry Standard |
Chemical Formula |
C3H5KOS2 |
ISO 9001:2015 / Custom Analysis |
Appearance |
Pale yellow granules or powder |
Visual (ISO/ASTM D-1200) |
Purity (%) |
≥90.0 |
GB/T 24343-2009 |
Moisture (%) |
≤4.0 |
GB/T 24343 |
Free Alkali (%) |
≤0.2 |
Company/Customer Spec |
Solubility |
Readily soluble in water |
ISO 787/13 |
pH (1% solution) |
9-11 |
ISO 787/9 |
Recommended Dosage |
10–100 g/t ore |
Process Dependent |
Potassium Ethylxanthate: Technical Data Visualization
Manufacturing Process of Potassium Ethylxanthate (Process Flow Chart)
- 1. Raw Materials: Ethanol, KOH, Carbon Disulfide (CS2), Water;
- 2. Reactor Charging: Ethanol reacts with KOH to form potassium ethoxide;
- 3. CS2 Addition: Potassium ethoxide reacts with carbon disulfide under controlled temperature (10–15°C), forming potassium ethylxanthate;
- 4. Filtration and Washing: The slurry is filtered and washed to remove byproducts and residual alkali;
- 5. Drying and Packaging: Granules/powder are dried in sealed units and packed in moisture-proof drums.
Technology Advantages and Material Excellence
- High Selectivity & Reaction Efficiency: Potassium ethylxanthate offers rapid absorption on sulfide mineral surfaces, improving flotation yields.
- Material Consistency: Manufactured via precision batch control, meets ISO 9001:2015 and ANSI/ASTM process standards.
- Customization: Fine granule or powder form, adjustable purity (≥90% standard; custom at 92–95% on request).
- Corrosion Prevention: Incorporation of stabilizers extends shelf-life up to 12 months (unopened, dry conditions).
- Safety & Sustainability: Fully REACH certified, non-toxic when handled as directed; minimal residue post-processing.
- High Solubility: Facilitates rapid dispersion and assimilation in flotation circuits, reducing energy consumption and processing time.
Potassium Ethylxanthate vs. Alternative Xanthate Reagents: Product Comparison Table
Parameter |
Potassium Ethylxanthate (KEX) |
Sodium Ethylxanthate (SEX) |
Potassium Amyl Xanthate (PAX) |
Chemical Formula |
C2H5OCSSK |
C2H5OCSSNa |
C5H11OCSSK |
Common Purity (%) |
≥90 |
≥85 |
≥90 |
Flotation Strength |
Medium |
Medium |
Strongest |
Solubility |
Very Good |
Good |
Good |
Primary Application |
Sulfide Minerals (Cu, Pb, Zn) |
Zinc/Lead/Oxide Ores |
Gold, Copper Sulfides |
Stability (Shelf Life) |
12 months |
10 months |
12 months |
Environmental Compliance |
High (REACH/ISO) |
Medium |
High |
Application Distribution by Industry (Estimated 2023)
Manufacturers & Supplier Comparison (2024)
Manufacturer |
Annual Capacity (tons) |
Certifications |
Export Regions |
Product Customization |
Lead Time (days) |
Fizachem |
14,000 |
ISO 9001, REACH |
Asia, EU, Africa, Americas |
Granule/Powder, Custom Purity |
7–15 |
Chinese State Producers |
10,000+ |
ISO, SGS |
Global |
Standard Formulations |
10–20 |
India (Private) |
5,500 |
ISO 9001 |
South Asia, MEA |
Powder Only |
18–25 |
Europe (Select Firms) |
2,300 |
ISO, REACH |
EU, Americas |
Powder/Custom |
12–22 |
Custom Solutions & OEM Capabilities
- Custom Packaging: 25kg/50kg fiber drums, FIBC bags, palletization, anti-caking agent on request
- Formula Adjustment: Tailored purity (90–96%) based on ore mineralogy, with impurity reduction techniques
- Application Engineering: Technical lab support, in-field flotation performance optimization, digital dosage monitoring
- OEM & White Labeling: Bulk supply for global OEMs; compliant with ISO and customer-specific criteria
- Technical Training: On-site and online operator training for dosing, handling, and emergency procedures
Request Your Custom Solution
Application Cases: Industry Scenarios & Client Experiences
1. Copper Concentrate Upgrade – Chile
A leading Chilean mining group deployed potassium ethylxanthate in a polymetallic flotation plant, achieving a copper grade increase from 18.2% to 22.1% with a 9% reduction in reagent consumption vs sodium xanthate. Post-process water analysis met ISO 14001 effluent norms (Cu
2. Gold Ore Flotation Optimization – Kazakhstan
Potassium ethyl xanthate formula engineered for higher impurity ores raised gold recovery by 14.6%, with 0.07% lower residual xanthate detected in tailings compared to amyl variants. Client note: “Stable supply, predictable performance, supports our ISO 45001 compliance.”
3. Floatation in Coal Enrichment – South Africa
Utilization of potassium ethylxanthate (granular, 95% purity) improved fine coal recovery by 31%. Switch-over from sodium products yielded less frother residue and improved water recycling reliability.
4. Environmental Test – Metallurgical Complex, Germany
A collaborative trial with TÜV SÜD accredited labs confirmed NO detectable xanthate residues after 3-stage water treatment (ISO 17025-certified). Recommendation: "Potassium ethylxanthate offers a high-performing, eco-compliant collector for EU regulated operations."
5. OEM Support – Southeast Asia
Major OEMs leverage Fizachem’s rapid delivery (7–12 days avg), custom micronization, and white-label supply for regional partners, saving them 23% compared to international imports. End-users report increased reliability and reduced maintenance.
Potassium Ethylxanthate Preparation: Step-by-Step Process Explanation
- Batch Preparation: Carefully measure and combine ethanol and KOH at an optimized molar ratio; react in stainless steel reactor.
- Reaction with Carbon Disulfide: CS2 is introduced under chilled and inert (N2) conditions, ensuring exothermic rate control (
- Stirring and Reflux: Maintain agitation to ensure full conversion while monitoring pH and temperature for rate optimization.
- Solid Separation: After the reaction, solution is filtered, water-washed to purity specification, and free alkali is neutralized.
- Drying & Packaging: Moisture is reduced under vacuum or low-temp airflow before final packaging under a dry, nitrogenous atmosphere.
- Quality Control: Each batch undergoes laboratory testing (purity, pH, moisture, solubility) as per ISO 9001:2015 protocols.
Professional FAQ: Potassium Ethylxanthate Technical FAQ
Q1: What is the optimal storage condition for potassium ethylxanthate?
A: Store in a cool, dry, ventilated warehouse, away from moisture, heat, and acids. Container must remain tightly sealed to prevent hydrolysis and caking. (Industry norm: ≤25°C, RH ≤65%)
Q2: How to calculate dosage for a new flotation system?
A: Begin with 25–50g/t for copper ore, adjust by mineralogy and process circuit. Bench trials advised for dosage optimization.
Q3: What are the main hazardous decomposition products?
A: At elevated temperatures or acidic conditions, releases carbon disulfide and minor hydrogen sulfide. Strict adherence to safe operating practices and ISO safety protocols is needed.
Q4: What testing standards are referenced for product quality?
A: ISO 9001:2015, GB/T 24343-2009 (China), and ASTM D-1200 (visual) for chemical and physical specifications.
Q5: Can potassium ethylxanthate be shipped worldwide?
A: Yes, packaged and labeled per UN 3342 and IMDG codes for marine/air transport. Supplied with SDS/MSDS documentation for each batch.
Q6: What is the shelf life?
A: Up to 12 months when stored under recommended conditions, with retension sample testing every 3 months advised.
Q7: What aftersales technical support is available?
A: Fizachem provides 24/7 engineer support, documented SOPs, on-site or virtual commissioning, and reagent performance auditing for all client partners.
Delivery Time, Warranty & Customer Support
- Delivery Cycle: Global shipping within 7–15 business days for standard packaging; custom/OEM orders: 14–21 days.
- Warranty: All batches certified per ISO 9001:2015. Replacement guarantee for off-spec shipments as per contract.
- After-Sales: Dedicated technical manager, application technician visit, annual training, and regulatory documentation for compliance.
- Documentation: SDS, COA, Reach Certificate included—downloadable from the official KEX product page.
Conclusion & Industry References
Potassium Ethylxanthate stands out as an essential collector reagent, prized for purity, process customization, and environmental compliance. For modern mineral processing operations seeking industrial excellence, Potassium Ethylxanthate offers the optimal balance of performance, safety, and global support. Technical literature and anecdotal field feedback increasingly position it as the industry’s gold standard for sulfide ore flotation.